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| PIXE
(Particle Induced X-Ray Excitation) is a sensitive analytical
technique utilising x-ray fluorescence but without the background
often associated with electron or x-ray excitation techniques. PIXE
analysis can be made with a variety of excitation particle types,
but most commonly used are protons with energies of a few MeV which
can be produced from a medium sized Tandem Van der Graaff accelerator. |
Applications
PIXE
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| The
proton beam may be used for PIXE analysis either in a vacuum chamber
or, by allowing the beam to exit from the beam line through a thin
window, large samples may be analysed in air. Local He gas environments
may also be used. |
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| The
proton beam can be focussed to a small cross-section, and can also
be deflected to produce a scan of the sample object. In this way,
elemental maps can be created which can be superposed on an optical
image from a microscope. |
| For
x-ray detection a large area Si(Li)
detector is typically used (80mm²), mounted at a backward
angle relative to the incident beam to reduce the posibility of scattered
protons entering the detector. The PIXE excitation process produces
both x-rays and gamma rays. Since the x-ray spectrum is weighted heavily
towards the low energy end, a so called 'funny-filter', consisting
of an absorber disk with a smaller central hole, is often used to
preferentially reduce the low energy transmission. |
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Typical
80mm² Si(Li) detector for PIXE applications. Shown mounted
on a manual slide with vacuum chamber interface. The base plate
is
used for mounting the detector for 'in-air' analysis.
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